Sunday, August 16, 2009

CO2 to fuels and chemicals

The GCC has an article on the "Advances in CO2 conversion and utiization" symposium at the ongoing American Chemical Society (ACS) National Meeting in Washington DC. This is a topic that is/was close to my research interests for the past six years, and more on it will soon follow. For now, here is the link to the GCC description of some of the talks. Also, I recently published a review article on the physics and chemistry behind the light-mediated conversion of CO2 to fuels on titanium-based materials in Energy and Environmental Science. You can find the open-access article at this link

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Monday, June 29, 2009

Electricity Load Reduction

I am just reposting an article from Penn State Newswire about Electricity Load Reduction tests conducted on campus. Penn State is a large commercial facility, with several thousand employees and tens of thousands of students on campus. In that sense, a 10% reduction (details below) is a fairly large amount if it can be sustained on a regular basis.
Electricity load reduction test a success

Last week, employees and students across Penn State's University Park campus were asked to simultaneously turn off all unnecessary electrical devices for one hour as a part of a regional electricity load reduction test. The test was a success -- the Office of Physical Plant (OPP) recorded an average reduction in electricity usage of 10 percent (3,700 kw).
The success was attributed to the many employees and students who cooperated by turning off unnecessary equipment and to OPP workers who made system-wide adjustments behind the scenes. The peak reduction for the hour was an impressive 15 percent (5000 kw) at 4 p.m.

Read the full story on Live: http://live.psu.edu/story/40286/nw63

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Monday, June 22, 2009

Guest post: Is public transportation (or the lack of it) a CATAstrophe?

The following is a guest post by Bhaskar, who authors the Speak Out blog. An unabridged version of this article can be found there.

In this economic downturn, and automotive industries taking such a hard hit, many people are talking about alternative sources of energy, hybrid vehicles, solar panels etc. I understand it is necessary to invest more in this resource. I find it really hard to digest the fact that the automakers-GM, Chevy who once ruled the market and profits in America are now really on the debacle, filing for bankruptcy. Obama government is doing all possible things to save this industry.
However, the idea of this post was not to discuss possibilities and changes that could be brought out. I am trying to focus on the public transportation system in my city- State College, the home of the Pennsylvania State University, a highly acclaimed university.

Its better to invest in public transportation, mass transit facilities, rail lines etc, than to focus on bringing newer cars into the market. We do have a buses in State college that helps people travel from place to place. However, we need to realize that State college is merely an university town and most people staying here are students.
CATA, as they call it,stands for Center Area Transportation Authority. The best part of this system is that the buses run clean, burning compressed natural gas. Hence, I feel that in a small way, we are trying to be eco-conscious. However, I am against this system for the fact that its too expensive to ride the bus.

I tried working out a balance sheet for the month and this is what I found.

Buying a pass for the month on the CATA line : $ 49
If you own a car and drive to school daily, (You anyways pay for the car insurance even if you do not drive to school), then
cost of fuel for the entire month= $25
Parking cost at the univ = $8 /month
Total= $ 33

This results in a saving of $16 a month. Which on an annual basis reflects to about $185.

This just goes to show that CATA bus service is really expensive. For a transit system that is funded by the county or the state, these services must be cheap. Infact, in many universities, local bus rides are free if you flash your ID.

So what motivates me against taking the bus?

If I drive to school, I can leave home at the time I want. This means that my schedule does not depend on the bus timings. Also, I get to save 15 to 20 bucks a month, depending on how much i drive.

If you are a staff at PSU, you definitely earn more than students, and CATA charges them just 5 bucks a month on the monthly pass. How logical is this?

I'd rather burn more fuel on my car (which I feel sad to say since I am an automotive engineer), but then I am justified in doing so.

Is there a solution to this?

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Monday, June 1, 2009

The role of energy in organic farming

I love listening to NPR. One article featured in their Morning Edition related to Indian farmers going organic in Punjab, the "breadbowl" of India. You can download the mp3 here. This post presents some of my comments on the article.

The farmer who the reporter talked to reportedly switched to organic farming because he was getting marginally diminishing returns with each application of pesticides and fertilizers. This means that to maintain crop yields, one must use more pesticides and fertilizers every year. Now, I do not find anything wrong with using fertilizers and pesticides, as long as they are used wisely. However, farmer literacy about agrochemical use in India is sorely lacking. Moreover, the government subsidizes fertilizer prices for the farmers, thereby indirectly contributing to their overuse. Additionally, because the cost to the farmer varies directly with both unit cost of fertilizer (which has not been changed for many years, despite the wild swings in energy prices over the past 9 years) and the quantity consumed, even an increase in the amount of fertilizer/pesticide used per unit area can be a financial burden to the farmer. Therefore, in some cases, it makes sense to go organic altogether.


However, as the Punjab State Farmers' Association report noted, widespread adoption of organic farming will likely lead to short-term food shortages, because of reduced yields in the most productive farms. Therefore, I think that India should slowly shift away from farm subsidies, promote organic farming -but not to the extent that it would lead to short-term food shortages, and finally promote smarter use of resources, both agrochemicals as well as water. Examples include growing crops which fix nitrogen along with crops which require nitrogen, such as beans with wheat, and soybeans with corn.


"Environmental groups in India estimate that more than 300,000 farmers like Sharma have switched to organic growing methods in recent years, or have started the transition from conventional to organic farming. Comparisons between India and the U.S. are difficult because their economies and cultures are so different. But consider this: India has about three times the population of the U.S., but 30 times more organic farmers than the U.S."

The average farm size in India is a fraction of that in the U.S.

Nitrogen fertilizers are a double edged sword because firstly, the production of ammonia (from which most urea-based fertilizers are made) emits CO2 (by processes such as naphtha steam reforming). Moreover, after the nitrogen fertilizers are applied to the soil, the urea is oxidized to nitrates and nitrites. When fertilizers are over-applied, these nitrates are washed off into rivers, causing algal blooms and utrophication. On the other hand, the Haber process for the manufacture of ammonia is credited with increasing the crop productivity in many parts of the world. This is a question for future world leaders: How do we balance the need to feed our growing population with the need to promote smarter use of resources and prevent unintended consequences?


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Monday, May 18, 2009

Change at the Energy Engineering Blog

I have graduated from Penn State and now work for a contract research/eng organization. This means that the frequency of my postings would be a bit lower. Also, I plan to highlight issues of energy conservation at home/office in some of my posts, now that I am paying both electric and water charges in my new apartment. So long, and hope to write a proper post soon!

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Friday, April 17, 2009

GHG update: EPA's endangerment finding & Pew Center's analysis of Waxman-Markey draft

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Thursday, April 16, 2009

Book Review: "Energy & International War: From Babylon to Baghdad & Beyond"



The author presents a somewhat academic description of the role played by access to (both fossil fuel and other mineral) resources in international conflicts. Not withstanding the numerous typos, the book is interesting from a historic as well as future-energy policy standpoint. For example, the author describes how access to the iron and coal-rich Alsace-Lorraine region shaped the frontline positions during WW I, how the conversion of British naval fleet from coal to oil gave them an advantage over the Germans before WW I, how the inferiority of the German Fischer-Tropsch aviation fuel contributed to their defeat in the Battle of Britain during WW II, and how Japanese pre-war thinking was heavily influenced by access to energy and mineral resources in south east Asia. On a more contemporary note, the author examines the current war in Iraq and presents some interesting conclusions. Additionally, natural gas, uranium and renewables markets are also explored in a similar vein. French foreign policy towards uranium-producing countries in Africa, and its role in civil/international regional conflicts is discussed. The author notes that after being assured of a dependable world supply for uranium, French policy has undergone a sea-change. The author discusses natural gas markets and the relations of the biggest supplier (Russia) with its former client states and Western European consumers.
The author notes that the European Union evolved from the European Coal and Steel Community, which was established to prevent future wars between France and Germany. One theme expressed in this book is that energy rarely is the main driver for international conflict, however, access to energy resources does play a role in shaping them, or as in WW I and II, influences their eventual outcomes.

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Sunday, April 12, 2009

Curiouser and curiouser!: Underground Coal-to-Liquids (UCTL) pilot test


UCTL Process flow diagram (click for an enlarged picture), source


The GCC reports that Regal Resources, an Australian company, is planning to acquire Magma Oil, which holds patents in underground coal-to-liquids (UCTL) processes. According to Magma Oil, hydrothermal reactions of coal (lignites) in the presence of suitable catalysts produce steam, methane and hydrocarbon liquids. The hydrocarbon liquids are separated for further refinery processing, whereas the steam (and other products) are reinjected. According to Magma Oil, the advantages of the process are the use of oilfield equipment (significantly lower capital costs compared to surface- and underground coal gasification technologies)and lower temperature (350 C), maximizing liquid hydrocarbon yields.
My comments
One cannot strictly compare the UCTL process to UCG (underground coal gasification) process. UCG technology aims to utilize stranded coal resources (not necessarily limited to lignites), and therefore requires some capital outlay for advanced (horizontal) drilling equipment. On the other hand, from the information available, it seems that the UCTL process works with mineable coal seams as well (seam depth > 50 m). Whereas previous UCG pilot tests have established to some level of certainty that groundwater pollution can be avoided, this is doubly important for the UCTL technologies where significantly higher quantities of water and other chemicals (catalysts) are likely injected. Other competitors to UCTL processes include the Syntroleum-Linc Energy air-based UCG-synfuel process also produces above-ground Fischer-Tropsch liquids from air-blown UCG syngas.
Two other issues might also be important: namely, the availability of supplementary "natural catalysts/impurities located in all coal seams" (coals are necessarily heterogeneous) and the real extent of zeolite-formation and CO2 sequestration.

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